تولید بیودیزل از روغن ضایعات ماهی به کمک ترکیب همزن مکانیکی و ریزموج

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه مهندسی مکانیک بیوسیستم، دانشگاه رازی، کرمانشاه، ایران

2 عضو هیات علمی دانشگاه رازی کرمانشاه

3 گروه مهندسی مکانیک بیوسیستم ، دانشگاه رازی، کرمانشاه،ایران

4 گروه مهندسی بیوسیستم، دانشکده کشاورزی، دانشگاه شهید چمران اهواز، اهواز، ایران

چکیده

در تحقیق حاضر هدف تولید بیودیزل از روغن ضایعات ماهی و متانول و استفاده از ترکیب همزن و ریز‌موج به عنوان تکنیکی برای سرعت بخشیدن به این امر می‌باشد. در انجام این تحقیق از سامانه‌ی ریز‌موج استفاده شد که شامل منبع ریزموج، همزن، لوله‌ی مارپیچی و دکانتور می‌باشد. به کمک این سامانه اثر عوامل نسبت مولی الکل به روغن (4 به 1، 6 به 1 و 8 به 1)، غلظت کاتالیزور (5/0، 1 و 5/1 درصد وزنی روغن)، زمان همزنی (5، 15 و 25 دقیقه) و زمان مایکروویو (5/0، 5/1 و 5/2 دقیقه) بر روی درصد تبدیل اسیدهای چرب به متیل استر بررسی شد. برای تجزیه و تحلیل نتایج از روش سطح پاسخ (RSM) و طرح باکس بنکن (Box Behnken) در نرم افزار Deisign Exeprt استفاده شد. پس از تحلیل داده‌ها و بهینه سازی واکنش تولید بیودیزل مشخص شد که بیشترین درصد تبدیل بیودیزل (62/92) در غلظت کاتالیزور 13/1%، زمان واکنش 61/24 دقیقه، نسبت مولی الکل به روغن 91/5 و زمان مایکروویو 5/0 دقیقه به دست آمد. مدل رگرسیونی بین متغیرهای مستقل و متغیر وابسته (درصد تبدیل) به صورت معادله درجه دوم با ضریب تبیین 9953/0=R2 به دست آمد.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Biodiesel production from fish waste oil by combination of mechanical stirrer and microwave

نویسندگان [English]

  • neda yari 1
  • leila naderloo 3
  • Seyed Mohammad Safieddin Ardebili 4
1 Mechanics of Biosystems Engineering Department, Agricultural Engineering Faculty, Razi University, Kermanshah, Iran
2
3 Mechanics of Biosystems Engineering Department, Agricultural Engineering Faculty, Razi University, Kermanshah, Iran
4 Biosystem Engineering Dept. Shahid Chamran University. Ahvaz, I.R. of Iran.
چکیده [English]

The purpose of the present study is to produce biodiesel from fish waste oil and methanol by combination of mechanical stirrer and microwave as a technique to accelerate this. In this research, a microwave system was used including microwave source, stirrer, spiral tube and decantor. With the help of this system, the effect of molar ratio of alcohol to oil (4 to 1, 6 to 1 and 8 to 1), catalyst concentration (0.5, 1 and 1.5 weight percent of oil), reaction time (5, 15 and 25 min) and microwave time (0.5, 1.5 and 2.5 min) on the conversion of fatty acid to methyl ester. For analyzing the obtained results, the response surface method and Box Behnken layout were used in Design Expert 10.0 software. After analyzing the data and optimizing the biodiesel production reaction, it was found that the highest percentage of biodiesel conversion (92.62%) was found in the catalyst concentration of 1.13%, the reaction time of 24.61, the molar ratio of alcohol to oil of 5.55 and the microwave time of 0.5 minute. The regression model between independent variables and dependent variable (percent conversion) was obtained as a quadratic equation with R2 = 0.9953.

کلیدواژه‌ها [English]

  • Biodiesel
  • Fish waste oil
  • Transesterification
  • Microwave
  • response surface method

مراجع

 

1.      N. Mrad, E. G. Varuvel, M. Tazerout and F. Aloui, “Effects of biofuel from fish oil industrial residue diesel blend in diesel engine,” Energy, 44, 2012, pp. 955-963.
2.      P. S. Nigam and A. Singh. “Production of liquid biofuels from renewable resources,” Progress in Energy and Combustion Science, 2011, pp. 52-68.
3.      L. Gao, G. Tang, G. Xiao and R. Wei, “Biodiesel from palm oil via loading KF/CA-AL hydrotalcite catalyst,” Bioenergy, 34, No. 9, 2012, pp. 1283-1288.
4.      Y. Li, F. Qiu, D. Yang, P. Sun and X. Li, “Transesterification of soybean oil and analysis of bioproduct,” Food and Bioproduct Processing, 90, 2012, pp. 135-140.
5.      P. Shao, X. Meng, J. He and P. Sun, “Analysis of immobilized candida rugose lipase catalyzed preparation of biodiesel from rapeseed soapstock,” Food and Bioproducts Processing, 86, No. 4, 2008, pp. 283-289.
6.      Y. Li, F. Qiu, D. Yang, X. Li and P. Sun, “Preparation, characterization an application of heterogeneous solid base catalyst for biodiesel production from soybean oil,” Biomass and Bioenergy, 35, No.7, 2011, pp. 2787-2795.
7.      D. Y. C. Leung, X. Wu and M. K. H. Leung, “Areview on biodiesel production using catalyzed transesterification,” Applied Energy, 87, No. 4, 2010, pp. 1083-1095.
8.      A. Kleinova, I. Vailing, J. Labaj, J. Mikulec and J. Cvengros, “Vegetable oils and animal fats as alternative fuels for diesel engines with dual fuel operation,” Fuel Processing Technology, 92, 2011, pp. 1980-1986.
9.      P. Adewale, M. J. Dumont and M. Ngadi, “Recent trends of biodiesel production from animal fat wastes and associated production techniques,” Renewable and Sustainable Energy Reviews, 45, 2015, pp. 574-588.
10.   N. Martini and S. Schell, Plant oil as fuels: Present state of future developments, First Edition, Germany, Berlin, springer, 1998.
11.   P. Felizardo, M. J. N. Correia, I. Raposo, J. F. Mendes, R. Berkemeier and J. M. Bordado, “Production of biodiesel from waste frying oils,” Waste Management, 26, 2006, pp. 487-494.
12.   J. V. Gerpen, “Biodiesel processing and production,” Journal of Fuel Processing Technology, 86, 2005, pp. 1097-1107.
13.   S. K. Karmee and A. Chadha, “Preparation of biodiesel from crude oil of pongamia pinnata,” Journal of Bioresource Technology, 96, 2005, pp. 1425-1429.
14.   P. Rose and M. Norris,Evaluate biodiesel made from wastes fats and oils, Final Report, Agriculture Utilization Research Institute, Crookston, MN, USA, 2002.
15.   G. Vicente, M. Matinez and J. Aracil, “Integrated biodiesel production: a comparison of different homogeneous catalysts systems,” Bioresource Technology, 92, 2004, pp. 297-305.
16.   H. Y. Shin, S. H. Lee, J. H. Ryu and S. Y. Bae, “Biodiesel production from waste lard using supercritical methanol,” The Journal of Supercritical Fluids, 61, 2012, 134-138.
17.   L. K. Ong, A. Kurniawan. A. C. Suwandi, C. X. Lin, X. S. Zhao and S. Ismadji, “Transesterification of leather tanning waste to biodiesel at supercritical condition: kinetics and thermodynamics studies,” The Journal of Supercritical Fluids, 75, 2013, pp. 11-20.
18.   N. Kapilan and B. Baykov, “A review on new methods used for the production of biodiesel,” Petroleum & Coal, 56, No. 1, 2014, pp. 62-73.
19.   G. Vicente, M. Martinez and J. Aracil, “Optimisation of integrated biodiesel production, Part I: A study of the biodiesel purity and yield,” Bioresource technology, 98, No. 9, 2007, pp.1724-1733.
20.   A. K. Singh, S. D. Fernando and R. Hernandez, “Base-catalyzed fast transesterification of soybean oil using ultrasonication,” Energy Fuel, 21, 2007, pp. 1161-1164.
21.   D. M. Pranjali and B. Dorin, “Investigation of microwave dielectric properties of biodiesel components,” Bioresource Technology, 127, 2013, pp. 1665-174.
22.   L. M. Das and P. K. Sahoo, “Combustion analysis of jatropha, karanja and polanga based biodiesel as fuel in a diesel engine,” Fuel, 88, 2008, pp. 994-999.
23.   P. Patil, H. Reddy, T. Muppaneni, S. Ponnusamy, Y. Sun, P. Dailey, P. Cook, U. Patil and S. Deng, “Optimization of microwave-enhanced methanolysis of algal biomass to biodiesel under temperature controlled conditions,” Bioresource Technology, 137, 2013, pp. 278-285.
24.   R. Priambodo, T. C. Chen, M. C. Lu, A. Gedanken, J. D. Liao and Y. H. Huang, “Novel technology for biodiesel production from cooking and waste cooking oil by microwave irradiation,” Energy procedia, 75, 2015, pp. 84-91.
25.   M. Zare, B. Ghobadian, E. Fayyazi, GH. Najafi and B. Hosseinzadeh, “Microwave-assisted biodiesel fuel production from waste cooking oil,” International Journal of Agriculture and Crop Sciences, 5, No. 12, 2013, pp. 1314-1317.
26.   R. Yahyaee. B. Ghobadian and G. Najafi, “Waste fish oil biodiesel asasource of renewable fuel in Iran,” Renewable And Sustainable Energy Reviews, 17, 2013, pp. 312-319.
27.   F. Preto, F. Zhang, and J. Wang, “A study on using fish oil as an alternative fuel for conventional combustors,” Fuel, 87, 2008, pp. 2258-2268.
28.   Y. L Cherng, and J. Rong, “Fuel properties of biodiesel produced from the crude fish oil from the soap stock of marine fish,” Fuel Processing Technology, 90, 2009, pp. 130-136.
29.   M. J. Dias, M. C. M. Alvim-Ferraz and M. F. Almeida, “Production of biodiesel from acid waste lard,” Bioresource Technology, 100, No. 24, 2009, pp. 6355-6361.
30.   J. F. Costa, M. F. Almeida, M. C. M. Alvim-Ferraz and J. M. Dias, “Biodiesel production using oil from fishcanning industry wastes,” Energy conversion and management, 74, 2013, pp. 17-23.
31.   C. S. Yogesh, S. Bhaskar, M. Devarapaga, L. Yun and Y. Zahira, “Fast Synthesis of High Quality Biodiesel from ‘Waste Fish Oil’ by Single Step Transesterification,” Biofuel Research Journal, 3, 2014, pp. 78-80.
32.   A. Demirbas, “Biodiesel production via non-catalytic SCF method and biodiesel fuel characteristics,” Energy Conversion andManagement, 47, No. 15, 2006, pp. 2271-2282.
33.   A. Demirbas, Biodiesel: a realistic fuel alternative for diesel engines, Springer-Verlag London Limited, London, 2008.
34.   N. Azcan, and O. Yilmaz, “Microwave irradiation application in biodiesel production from promising biodiesel fedstock microalgae,” Proceedings of the world congress on engineering and computer science, WCECS 2012, October 24-26, 2012, San Francisco, USA.
 

 

1.      N. Mrad, E. G. Varuvel, M. Tazerout and F. Aloui, “Effects of biofuel from fish oil industrial residue diesel blend in diesel engine,” Energy, 44, 2012, pp. 955-963.
2.      P. S. Nigam and A. Singh. “Production of liquid biofuels from renewable resources,” Progress in Energy and Combustion Science, 2011, pp. 52-68.
3.      L. Gao, G. Tang, G. Xiao and R. Wei, “Biodiesel from palm oil via loading KF/CA-AL hydrotalcite catalyst,” Bioenergy, 34, No. 9, 2012, pp. 1283-1288.
4.      Y. Li, F. Qiu, D. Yang, P. Sun and X. Li, “Transesterification of soybean oil and analysis of bioproduct,” Food and Bioproduct Processing, 90, 2012, pp. 135-140.
5.      P. Shao, X. Meng, J. He and P. Sun, “Analysis of immobilized candida rugose lipase catalyzed preparation of biodiesel from rapeseed soapstock,” Food and Bioproducts Processing, 86, No. 4, 2008, pp. 283-289.
6.      Y. Li, F. Qiu, D. Yang, X. Li and P. Sun, “Preparation, characterization an application of heterogeneous solid base catalyst for biodiesel production from soybean oil,” Biomass and Bioenergy, 35, No.7, 2011, pp. 2787-2795.
7.      D. Y. C. Leung, X. Wu and M. K. H. Leung, “Areview on biodiesel production using catalyzed transesterification,” Applied Energy, 87, No. 4, 2010, pp. 1083-1095.
8.      A. Kleinova, I. Vailing, J. Labaj, J. Mikulec and J. Cvengros, “Vegetable oils and animal fats as alternative fuels for diesel engines with dual fuel operation,” Fuel Processing Technology, 92, 2011, pp. 1980-1986.
9.      P. Adewale, M. J. Dumont and M. Ngadi, “Recent trends of biodiesel production from animal fat wastes and associated production techniques,” Renewable and Sustainable Energy Reviews, 45, 2015, pp. 574-588.
10.   N. Martini and S. Schell, Plant oil as fuels: Present state of future developments, First Edition, Germany, Berlin, springer, 1998.
11.   P. Felizardo, M. J. N. Correia, I. Raposo, J. F. Mendes, R. Berkemeier and J. M. Bordado, “Production of biodiesel from waste frying oils,” Waste Management, 26, 2006, pp. 487-494.
12.   J. V. Gerpen, “Biodiesel processing and production,” Journal of Fuel Processing Technology, 86, 2005, pp. 1097-1107.
13.   S. K. Karmee and A. Chadha, “Preparation of biodiesel from crude oil of pongamia pinnata,” Journal of Bioresource Technology, 96, 2005, pp. 1425-1429.
14.   P. Rose and M. Norris,Evaluate biodiesel made from wastes fats and oils, Final Report, Agriculture Utilization Research Institute, Crookston, MN, USA, 2002.
15.   G. Vicente, M. Matinez and J. Aracil, “Integrated biodiesel production: a comparison of different homogeneous catalysts systems,” Bioresource Technology, 92, 2004, pp. 297-305.
16.   H. Y. Shin, S. H. Lee, J. H. Ryu and S. Y. Bae, “Biodiesel production from waste lard using supercritical methanol,” The Journal of Supercritical Fluids, 61, 2012, 134-138.
17.   L. K. Ong, A. Kurniawan. A. C. Suwandi, C. X. Lin, X. S. Zhao and S. Ismadji, “Transesterification of leather tanning waste to biodiesel at supercritical condition: kinetics and thermodynamics studies,” The Journal of Supercritical Fluids, 75, 2013, pp. 11-20.
18.   N. Kapilan and B. Baykov, “A review on new methods used for the production of biodiesel,” Petroleum & Coal, 56, No. 1, 2014, pp. 62-73.
19.   G. Vicente, M. Martinez and J. Aracil, “Optimisation of integrated biodiesel production, Part I: A study of the biodiesel purity and yield,” Bioresource technology, 98, No. 9, 2007, pp.1724-1733.
20.   A. K. Singh, S. D. Fernando and R. Hernandez, “Base-catalyzed fast transesterification of soybean oil using ultrasonication,” Energy Fuel, 21, 2007, pp. 1161-1164.
21.   D. M. Pranjali and B. Dorin, “Investigation of microwave dielectric properties of biodiesel components,” Bioresource Technology, 127, 2013, pp. 1665-174.
22.   L. M. Das and P. K. Sahoo, “Combustion analysis of jatropha, karanja and polanga based biodiesel as fuel in a diesel engine,” Fuel, 88, 2008, pp. 994-999.
23.   P. Patil, H. Reddy, T. Muppaneni, S. Ponnusamy, Y. Sun, P. Dailey, P. Cook, U. Patil and S. Deng, “Optimization of microwave-enhanced methanolysis of algal biomass to biodiesel under temperature controlled conditions,” Bioresource Technology, 137, 2013, pp. 278-285.
24.   R. Priambodo, T. C. Chen, M. C. Lu, A. Gedanken, J. D. Liao and Y. H. Huang, “Novel technology for biodiesel production from cooking and waste cooking oil by microwave irradiation,” Energy procedia, 75, 2015, pp. 84-91.
25.   M. Zare, B. Ghobadian, E. Fayyazi, GH. Najafi and B. Hosseinzadeh, “Microwave-assisted biodiesel fuel production from waste cooking oil,” International Journal of Agriculture and Crop Sciences, 5, No. 12, 2013, pp. 1314-1317.
26.   R. Yahyaee. B. Ghobadian and G. Najafi, “Waste fish oil biodiesel asasource of renewable fuel in Iran,” Renewable And Sustainable Energy Reviews, 17, 2013, pp. 312-319.
27.   F. Preto, F. Zhang, and J. Wang, “A study on using fish oil as an alternative fuel for conventional combustors,” Fuel, 87, 2008, pp. 2258-2268.
28.   Y. L Cherng, and J. Rong, “Fuel properties of biodiesel produced from the crude fish oil from the soap stock of marine fish,” Fuel Processing Technology, 90, 2009, pp. 130-136.
29.   M. J. Dias, M. C. M. Alvim-Ferraz and M. F. Almeida, “Production of biodiesel from acid waste lard,” Bioresource Technology, 100, No. 24, 2009, pp. 6355-6361.
30.   J. F. Costa, M. F. Almeida, M. C. M. Alvim-Ferraz and J. M. Dias, “Biodiesel production using oil from fishcanning industry wastes,” Energy conversion and management, 74, 2013, pp. 17-23.
31.   C. S. Yogesh, S. Bhaskar, M. Devarapaga, L. Yun and Y. Zahira, “Fast Synthesis of High Quality Biodiesel from ‘Waste Fish Oil’ by Single Step Transesterification,” Biofuel Research Journal, 3, 2014, pp. 78-80.
32.   A. Demirbas, “Biodiesel production via non-catalytic SCF method and biodiesel fuel characteristics,” Energy Conversion andManagement, 47, No. 15, 2006, pp. 2271-2282.
33.   A. Demirbas, Biodiesel: a realistic fuel alternative for diesel engines, Springer-Verlag London Limited, London, 2008.
34.   N. Azcan, and O. Yilmaz, “Microwave irradiation application in biodiesel production from promising biodiesel fedstock microalgae,” Proceedings of the world congress on engineering and computer science, WCECS 2012, October 24-26, 2012, San Francisco, USA.
 

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  • تاریخ دریافت: 27 شهریور 1396
  • تاریخ بازنگری: 14 آبان 1396
  • تاریخ پذیرش: 15 آبان 1396

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