Studying the Influence of Temperature and Residence Time on the Recovery of Oil Filter Components via Pyrolysis

Document Type : Original Article

Authors

1 Chemical Engineering Department, Tarbiat Modares University, Tehran, Iran

2 Tarbiat Modares University

10.22034/jfnc.2024.425226.1365

Abstract

Used oil filters contain both significant environmental hazards and valuable components suitable for reuse, justifying their recycling. Among various recycling methods, pyrolysis has been employed in this project. This study investigates the behavior of each influential material in residue production, including used oil, rubber gasket, and filter paper, with the alteration of two parameters: temperature and residence time, individually. Experiments were conducted at temperatures of 360, 440, and 520 degrees Celsius, with two residence times of 30 and 90 minutes, under a constant nitrogen flow rate of 200 ml/min. The residue yield was measured after each experiment. In the pyrolysis of used oil, with an increase in temperature and residence time, the residue production initially decreased due to the advancement of primary thermal cracking reactions in the feed. However, secondary thermal cracking of hydrocarbons present in the reactor led to a subsequent increase in residue production. In the pyrolysis of rubber gasket, the residue production trend consistently decreased with rising temperature and residence time, indicating the progression of pyrolysis and initial thermal cracking, as well as the vaporization of solid hydrocarbon materials at higher temperatures. In the examination of the effect of temperature and residence time on filter paper pyrolysis, it was observed that increasing these parameters reduced the efficiency of residue production. This reduction could be attributed to either the initial thermal cracking of the filter paper or the secondary thermal cracking of the produced residue.

Keywords

Main Subjects


[1]  O. Hanoshenko, O. Stepova, Y. Chukhlib, L. Kostiantyn, Y. Yanovych, and N. Bilotserkivsk, “Environmentally friendly disposal of used automotive oil filters: legislative aspects and technology,” Ecol. Quest., vol. 32, pp. 77–89, 2021.
[2]  K. D. Peaslee, “Recycling used automotive oil filters,” JOM, vol. 46, pp. 44–46, 1994.
[3]  “www.irna.ir/news/84299320/.”
[4]  Small Industries Organization and industrial States of Iran. Preliminary feasibility studies of the recycling plan automobile oil filters. (in Persian)
[5]  A. Babich and D. Senk, “ Coke in the iron and steel industry,” in New Trends in Coal Conversion, Chapter 13, pp. 367–404, 2019.
[6]  “https://www.markazeahan.com/iron-scrap-market-situation.”
[7]  G. Gaidajis, K. Angelakoglou, P. N. Botsaris, and F. Filippidou, “Analysis of the recycling potential of used automotive oil filters using the Life Cycle Assessment approach,” Resour. Conserv. Recycl., vol. 55, pp. 986–994, 2011,
[8]  K. D. Peaslee and D. E. Roberts, “The Future of Used Oil Filter Recycling in Missouri: An Evaluation of Potential Processes, Product Quality, Recycling Locations, and Economics,” 1997.
[9]  A. V Bridgwater, “Principles and practice of biomass fast pyrolysis processes for liquids,” J. Anal. Appl. Pyrolysis, vol. 51, pp. 3–22, 1999.
[10]   J. Towfighi, S. M. Sadrameli, and A. Niaei, “Coke Formation Mechanisms and Coke Inhibiting Methods in Pyrolysis Furnaces,” J. Chem. Eng. Japan , vol. 35, pp. 923–937, 2002
[11]   M. L. Poutsma, “Fundamental reactions of free radicals relevant to pyrolysis reactions,” J. Anal. Appl. Pyrolysis, vol. 54, no. 1–2, pp. 5–35, 2000.
[12]   A. Corma, L. Sauvanaud, Y. Mathieu, S. Al-Bogami, A. Bourane, and M. Al-Ghrami, “Direct crude oil cracking for producing chemicals: Thermal cracking modeling,” Fuel, vol. 211, pp. 726–736, 2018.
[13]   S. S. Nagaraja, A. B. Sahu, S. Panigrahy, and H. J. Curran, “A fundamental study on the pyrolysis of hydrocarbons,” Combust. Flame, vol. 233, p. 111579, 2021.
[14]   P. E. Savage, “Mechanisms and kinetics models for hydrocarbon pyrolysis,” J. Anal. Appl. Pyrolysis, vol. 54, pp. 109–126, 2000.
[15]   J. Singh, S. Kumar, and M. O. Garg, “Kinetic modelling of thermal cracking of petroleum residues: A critique,” Fuel Process. Technol., vol. 94, pp. 131–144, 2012.
[16]   K. D. Peaslee and D. E. Roberts, “Characterization of used automotive oil filters for recycling,” Resour. Conserv. Recycl., vol. 19, pp. 81–91, 1997.
[17]   D. E. Roberts II and K. D. Peaslee, “Analysis of the factors influencing the removal of oil from used automotive oil filters during recycling operations,” Resour. Conserv. Recycl., vol. 22, pp. 97–113, 1998.
[18]   Y. Holik and E. Ganoshenko, “Experimental research of withdrawal of oil remains from the used kaolin oil filters,” Environmental problems, 2017.irbis-nbuv.gov.ua.
[19]   M. Hassanpour, “Technologies to Manage Used Automotive Oil Filters in Iran: A Review Study,” Arch. Hyg. Sci., vol. 10, pp. 97–110, 2021.
[20]   S. A. El-Mekkawi, N. N. El-Ibiari, N. K. Attia, G. I. El-Diwani, O. A. El-Ardy, and A. K. E. Morsi, “Reducing the environmental impact of used lubricating oil through the production of fuels by pyrolysis,” Environ. Nanotechnology, Monit. Manag., vol. 14, pp. 92-109, 2020.
[21]   S. S. Lam, A. D. Russell, and H. A. Chase, “Pyrolysis Using Microwave Heating : A Sustainable Process for Recycling Used Car Engine Oil,” pp. 10845–10851, 2010.
[22]   A. M. Cunliffe and P. T. Williams, “Composition of oils derived from the batch pyrolysis of tyres,” J. Anal. Appl. Pyrolysis, vol. 44, pp. 131–152, 1998,.
[23]   W. J. Dodds, J.; Domenico, W.F.; Evans, D.R.; Fish, L.W.; Lassahn, P.L.; Toth, "Scrap tires: a resource and technology evaluation of tire pyrolysis and other selected alternate technologies" U.S. Department of Energy ldaho Operations Office Under DOE Contract No. DE-AC07-761001570, 1983.