Fuel and Combustion

Fuel and Combustion

Statistical optimization using central composite design for the desilication process of natural zeolite to use in water adsorption from diesel fuel

Document Type : Original Article

Authors
Fatemeh Kouhestani 1
fatemeh Eslami 2
Ramin Karimzadeh 3
1 دانشگاه تربیت مدرس دانشکده مهندسی شیمی
2 Al ahmad St,Tarbiat Modares University, School of chemicaal engineering, 5th floor
3 Tarbiat Modares University
10.22034/jfnc.2019.104084
Abstract
In this paper, natural zeolite (clinoptilolite) was desilicated to remove water from diesel fuel. Optimization of desilication conditions was done using Design-Expert 7.0.0 software and using response surface methodology. The parameters studied, the concentration of sodium hydroxide solution and the temperature and time of the desilication process were considered. After optimization of desilication process conditions, the water sorption percentage was 95.32% under the optimized conditions, the concentration of sodium hydroxide solution 0.47 molar, temperature 84.05 °C and time of 2.42 hours. To carry out the process of water sorption from fuel, amount of 0.5% w/v of the desilicated zeolite (5 g zeolite/1000 mL of the fuel) was mixed with diesel fuel for 2 h and the water content was measured by the volumetric Karl Fischer technique. The natural zeolite and the desilicated zeolite in the optimum conditions were characterized by XRD, XRF, FTIR and SEM analyses which indicate well desilication process. The results of water sorption before and after the sorption process indicate the acceptable performance of desilicated zeolite.
Keywords
Clinoptilolite
Adsorption
Desilication
Diesel fuel
Central composite design

Subjects

  1. C. G. Tsanaktsidis, E. P. Favvas, A. A. Scaltsoyiannes, S. G. Christidis, E. X. Katsidi and A. V. Scaltsoyiannes, “Natural resins and their application in antifouling fuel technology: Part I: Improving the physicochemical properties of diesel fuel using natural resin polymer as a removable additive,” Fuel Processing Technology, 114, 2013, pp. 135–143.
  2. S. U. Patel and G. G. Chase, "Separation of Water Droplets from Water-in-Diesel Dispersion Using Superhydrophobic Polypropylene Fibrous Membranes,” Separation and Purification Technology, 126, 2014, pp. 62–68.
  3. X. Yang, H. Wang and G. G. Chase, “Performance of Hydrophilic Glass Fiber Media to Separate Dispersed Water Drops from Ultra Low Sulfur Diesel Supplemented by Vibrations,” Separation and Purification Technology, 156, 2015, pp. 665–672.
  4. P. Kusgens, Metal-Organic Frameworks for Water Adsorption Applications in The Automotive ltration Industry, PhD Thesis, Department of Mathematics and Natural Sciences, Technical University of Dresden, Dresden, 2009.
  5. X. Yang, X. Zhang, H. Wang and G. G. Chase, “Vibration Assisted Water-Diesel Separation by Electrospun PVDF-HFP Fiber Mats,” Separation and Purification Technology, 171, 2016, pp. 280–288.
  6. P. B. L. Fregolente and M. R. W. Maciel, “Water Absorbing Material to Removal Water from Biodiesel and Diesel,” Procedia Engineering, 42, 2012, pp. 1983–1988.
  7. P. B. L. Fregolente, “Removal of Water Content from Biodiesel and Diesel Fuel using Hydrogel Adsorbents,” Brazilian Journal of Chemical Engineering, 32, pp. 895–901, 2015.
  8. H. Nur, M. J. Snowden, V. J. Cornelius, J. C. Mitchell, P. J. Harvey, L. S. Benee, “Colloidal Microgel in Removal of Water from Biodiesel,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 335, 2009, pp. 133–137.
  9. D. Sun, X. Duan, W. Li and D. Zhou, “Demulsification of Water-in-Oil Emulsion by Using Porous Glass Membrane,” Membrane Science, Vol. 146, 1998, pp. 65–72.
  10. E. P. Favvas, C. G. Tsanaktsidis, A. A. Sapalidis, G. T. Tzilantonis, S. K. Papageorgiou and A. C. Mitropoulos, “Clinoptilolite, A Natural Zeolite Material: Structural Characterization and Performance Evaluation on Its Dehydration Properties of Hydrocarbon-Based Fuels,” Microporous and Mesoporous Materials, 225, 2016, pp. 385–391.
  11. S. Kesraoui‐Ouki, C. R. Cheeseman and R. Perry, “Natural Zeolite Utilisation in Pollution Control: A Review of Applications to Metals’ Effluents,” Chemical Technology & Biotechnology, 59, 1994, pp. 121–126.
  12. Chojnacki, K. Chojnacka, J. Hoffmann and H. Gorecki, “The Application of Natural Zeolites for Mercury Removal: from Laboratory Tests to Industrial Scale,” Minerals Engineering, 17, 2004, pp. 933–937.
  13. P. Misaelides, “Application of Natural Zeolites in Environmental Remediation: A Short Review,” Microporous and Mesoporous Materials, 144, 2011, pp. 15–18.
  14. M. W. Ackley, S. U. Rege and H. Saxena, “Application of Natural Zeolites in The Purification and Separation of Gases,” Microporous and Mesoporous Materials, 61, 2003, pp. 25–42.
  15. J. Weitkamp, “Zeolites and Catalysis,” Solid State Ionics, 131, 2000, pp. 175–188.
  16. N. Q. Feng and G. F. Peng, “Applications of Natural Zeolite to Construction and Building Materials in China,” Construction and Building Materials, 19, 2005, pp.579–584.
  17. N. Eroglu, M. Emekci and C. G.Athanassiou, “Applications of Natural Zeolites on Agriculture and Food Production,” Science of Food and  Agriculture, 97, 2017, pp. 3487–3499.
  18. D. Kalló, “Applications of Natural Zeolites in Water and Wastewater Treatment,” Reviews in mineralogy and geochemistry, 45, 2001, pp. 519–550.
  19. K. Margeta, N. Z. Logar, M. Šiljeg and A. Farkaš, Water Treatment, London, Intech Open, 2013.
  20. S. Wang and Y. Peng, “Natural Zeolites as Effective Adsorbents in Water and Wastewater Treatment,” Chemical Engineering Journal, 156, 2010, pp. 11–24.
  21. J. Pires and M. Brotas de Carvalho, “Water Adsorption in Aluminium Pillared Clays and Zeolites,” Materials Chemistry, 7, 1997, pp. 1901–1904.
  22. A. Jentys, G. Warecka, M. Derewinski and J. A. Lercher, “Adsorption of Water on ZSM-5 Zeolites,” Physical Chemistry, 93, 1989, pp. 4837–4843.
  23. M. Takeuchi, T. Kimura, M. Hidaka, D. Rakhmawaty and M. Anpo, “Photocatalytic Oxidation of Acetaldehyde with Oxygen on TiO2/ZSM-5 Photocatalysts: Effect of Hydrophobicity of Zeolites,” Catalysis, 246, 2007, pp. 235–240.
  24. [24]   A. Ates and G. Akgül, “Modification of Natural Zeolite with NaOH for Removal of Manganese in Drinking Water,” Powder Technology, 287, 2016, pp. 285–291.
  25. J. C. Groen, L. A. A. Peffer, J. Moulijn and J. Pérez-Ramı́rez, “On The Introduction of Intracrystalline Mesoporosity in Zeolites upon Desilication in Alkaline Medium,” Microporous and Mesoporous Materials, 69, 2004, pp. 29–34.
  26. H. Lin, Q. Liu, Y. Dong, Y. He and L. Wang, “Physicochemical Properties and Mechanism Study of Clinoptilolite Modified by NaOH,” Microporous and Mesoporous Materials, 218, 2015, pp. 174–179.
  27. J. C. Groen, L. A. A. Peffer, J. A. Moulijn and J. Pérez-Ramı́rez, “Mesoporosity Development in ZSM-5 Zeolite upon Optimized Desilication Conditions in Alkaline Medium,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 241, 2004, pp. 53–58.
  28. M. Akgül and A. Karabakan, “Promoted Dye Adsorption Performance Over Desilicated Natural Zeolite,” Microporous and Mesoporous Materials, 145, 2011, pp. 157–164.
  29. Y. Hou, C. T. Duan, N. Zhao, H. Zhang, Y. P. Zhao, L. Chen, H. J. Dai and J. Xu, “A Versatile Coating Approach to Fabricate Superwetting Membranes for Separation of Water-in-Oil Emulsions,” Chinese Journal of Polymer Science (English Edition), 34, 2016, pp.1234–1239.
  30. R. Mahmoudi and C. Falamaki, “A Systematic Study on The Effect of Desilication of Clinoptilolite Zeolite on its Deep-Desulfurization Characteristics,” Nanochemistry Research., 1, 2016, pp. 205–213.
  31. M. Cavazzuti, Optimization Methods, First Edition,Germany, Springer-Verlag Berlin Heidelberg, 2013.
  32. A. I. Khuri and S. Mukhopadhyay, “Response Surface Methodology,” WIREs Computational Statistics, 2, 2010, pp. 128-149.
  33. K. Hinkelmann and O. Kempthorne, Design and Analysis of Experiments, Second Edition, New Jersey, John Wiley & Sons, Inc., 2007.
  34. Z. H. Yang, J. Huang, G. M. Zeng, M. Ruan, C. S. Zhou, L. Li and Z. G. Rong, “Optimization of Focculation Conditions for Kaolin Suspension using the Composite Flocculant of MBFGA1 and PAC by Response Surface Methodology,” Bioresource Technology, 100, 2009, pp. 4233–4239.
  35. M. Kılıç, B. B. Uzun, E. Pütün and A. E. Pütün, “Optimization of Biodiesel Production from Castor Oil Using Factorial Design,” Fuel Processing Technology, 111, 2013, pp. 105–510.
  36. E. Kouvelos, K. Kesore, T. Steriotis, H. Grigoropoulou, D. Bouloubasi, N. Theophilou, S. Tzintzos and N. Kanelopoulos, “High Pressure N2/CH4 Adsorption Measurements in Clinoptilolites,” Microporous and Mesoporous Materials, 99, 2007, pp. 106–111.
  37. F. Pechar and D. Rykl, “Infrared Spectra of Natural Zeolites of The Stilbite Group,” Chemické Zvesti, 35, 1981, pp. 189-202.
  38. I. Othman Ali, “Preparation and Characterization of Copper Nanoparticles Encapsulated Inside ZSM-5 Zeolite and no Adsorption,” Materials Science and Engineering, 459, 2007, pp. 294–302.
  39. J. C. Groen, J. A. Moulijn and J. Pérez-Ramírez, “Desilication: on The Controlled Generation of Mesoporosity in MFI Zeolites,” Materials Chemistry, 16, 2006, pp. 2121–2131.